column 7 of the hazardous materials table

Column 7 contains special provisions associated with the hazardous material. 159 This material must be protected from direct sunshine and kept in a cool, well-ventilated place away from sources of heat. b. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. Navigate by entering citations or phrases However this examination is required when the conditions of 180.605(f) are met. a. B27 Tanks must have a service pressure of 1,034 kPa (150 psig). g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. c. Each glass inner packaging is protected by a means of preventing puncture of the plastic bag (e.g., sleeves or cushioning) in the event of damage to the packaging (e.g., by crushing). 129 These materials may not be classified and transported unless authorized by the Associate Administrator on the basis of results from Series 2 Test and a Series 6(c) Test from the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) on packages as prepared for transport. 160 This entry applies to safety devices for vehicles, vessels or aircraft, e.g. If you would like to comment on the current content, please use the 'Content Feedback' button below for instructions on contacting the issuing agency. Components classed as Division 6.1, Packing Group I, or Class 8, Packing Group I, must not be offered for transportation and transported under this description. 169 This entry applies to lighter refills (see 171.8 of this subchapter) that contain a Division 2.1 (flammable) gas but do not contain an ignition device. Pressing enter in the search box 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. Shipments made in accordance with this Special provision are excepted from the requirements of 173.60(b)(4) of this subchapter. 19 For domestic transportation only, the identification number UN1075 may be used in place of the identification number specified in column (4) of the 172.101 table. Specifically, you seek clarification on the implementation of special provision IP15which is listed in Column 7 of the 172.101 Hazardous Materials Table (HMT)as it applies when this material is packaged in a composite intermediate bulk container (IBC) with a rigid inner receptacle. TP26 The heating device must be exterior to the shell. 106 The recognized name of the particular explosive may be specified in addition to the type. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. 144 If transported as a residue in an underground storage tank (UST), as defined in 40 CFR 280.12, that has been cleaned and purged or rendered inert according to the American Petroleum Institute (API) Standard 1604 (IBR, see 171.7 of this subchapter), then the tank and this material are not subject to any other requirements of this subchapter. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. Lead-free Solder Figure 3: Engineer soldering a microcircuit Note, Tin here is the primary metal. B61 Written procedures covering details of tank car appurtenances, dome fittings, safety devices, and marking, loading, handling, inspection, and testing practices must be approved by the Associate Administrator before any single unit tank car tank is offered for transportation. (iii) T50 When portable tank instruction T50 is indicated in Column (7) of the 172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. e. When transported by highway, rail, vessel, or as cargo on an aircraft, neutron radiation detectors containing not more than 1 gram of boron trifluoride, including those with solder glass joints are not subject to any other requirements of this subchapter provided they meet the requirements in paragraph a of this special provision and are packed in accordance with paragraph b of this special provision. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. The quantities of hazardous materials do not exceed those specified in 173.4a of this subchapter; and. 385 Notwithstanding the provisions of 177.834(l) of this subchapter, cargo heaters may be used when weather conditions are such that the freezing of a wetted explosive material is likely. Interior heating coils are not authorized. that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. Insulating materials must not promote corrosion to steel when wet. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, the package must be marked as required for both battery types. A191 Notwithstanding the Division 6.1 subsidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the shipping paper are not required for manufactured articles containing less than 5 kg (11 pounds) of mercury. (2) To the extent a special provision imposes limitations or additional requirements on the packaging provisions set forth in column 8 of the 172.101 table, packagings must conform to the requirements of the special provision. A stimulating mechanism must be used to initiate one article in the middle of the packaging. TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. learn more about the process here. B130 When transported by motor vehicle, used diatomaceous earth filter material is not subject to any other requirements of this subchapter except for the shipping paper requirements of subpart C of part 172 of this subchapter; emergency response information as required by 172.602(a)(2) through (a)(7) of this subchapter; and the marking requirements of 172.302 of this subchapter, if the following requirements are met: a. Packagings are non-DOT specification sift-proof motor vehicles or sift-proof roll-on/roll-off bulk bins, which are covered by a tarpaulin or other equivalent means. 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. The tank must have been designed and constructed to be capable of withstanding full vacuum. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. Unless otherwise provided in this subchapter, these special provisions do not apply to UN, IM Specification portable tanks or IBCs. Formulations not meeting these criteria must be transported under the provisions applicable to the appropriate entry in the Organic Peroxide Table in 173.225 of this subchapter. 328 When lithium metal or lithium ion batteries are contained in the fuel cell system, the item must be described under this entry and the appropriate entries for Lithium metal batteries contained in equipment or Lithium ion batteries contained in equipment. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate; 0-5% sodium or potassium perchlorate; 0-17% hexamine nitrate or monomethylamine nitrate; 5-30% water; 2-15% fuel; 0.5-4% thickening agent; 0-10% soluble flame suppressants; and trace additives. Additionally, the offeror must notify the carrier if the tank pressure rise exceeds 3 psig over any 24-hour period. If they do leak, they must be overpacked in packagings conforming to the specification requirements of part 178 of this subchapter or in salvage packagings conforming to the requirements in 173.12 of this subchapter. The temperature of the material at the time it is offered for transport and during transportation may not exceed 55 C (130 F). This document is available in the following developer friendly formats: Information and documentation can be found in our 360 Vehicles powered only by lithium batteries must be described using UN3171, Battery-powered vehicle. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit, must be described using UN3536, Lithium batteries installed in a cargo transport unit., 361 Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. Note also that this exception does not apply to batteries that have been reconditioned for reuse. You can If appropriate, a package containing this material must conform to the additional labeling requirements of 172.402 of this subchapter. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. This entry may not be used for ammonium nitrate for which a proper shipping name already exists in the 172.101 Hazardous Materials Table, including ammonium nitrate mixed with fuel oil or any other commercial grade of ammonium nitrate (e.g., ammonium nitrate fertilizer). For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. (In the example, the special provision codes for toluene are IB2, T4 and TP1.) Component cells of the battery must be of a type proved to meet the respective testing requirements of the Manual of Tests and Criteria, part III, subsection 38.3 (IBR, see 171.7 of this subchapter). TABLE 2 lists . Other inorganic nitrate salts may replace part of the ammonium nitrate. (2) A code containing the letter A refers to a special provision which applies only to transportation by aircraft. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. All successfully conducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each authorized mode of transport in this special provision. B116 The use of non specification, sift-proof dump or hopper type vehicles, and sift-proof roll-on/roll-off bulk bins, which must be covered by a tarpaulin, metal cover, or equivalent means is authorized for the transportation of spent bleaching earth by motor vehicle. Hazardous materials not necessary for the safe and proper operation of the cargo transport unit must not be transported within the cargo transport unit. A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. d. A chemical under pressure with components meeting the properties of: Class 1 (explosives); Class 3 (liquid desensitized explosives); Division 4.1 (self-reactive substances and solid desensitized explosives); Division 4.2 (substances liable to spontaneous combustion); Division 4.3 (substances which, in contact with water, emit flammable gases or toxic gases); Division 5.1 (oxidizing substances); Division 5.2 (organic peroxides); Division 6.2 (Infectious substances); or, Class 7 (Radioactive material), must not be offered for transportation under this description. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. A60 Sterilization devices, when containing less than 30 mL per inner packaging with not more than 150 mL per outer packaging, may be transported in accordance with the provisions in 173.4a, irrespective of 173.4a(b), provided such packagings were first subjected to comparative fire testing. 172-123, 55 FR 52582, Dec. 21, 1990]. You are using an unsupported browser. B56 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized if the particle size of the hazardous material is not less than 149 microns. 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. PDF DOT CHART 16 Hazardous Materials Markings,Labeling and Placarding Guide b. Gases of Division 2.3 and gases with a subsidiary risk of 5.1 must not be used as a propellant in a chemical under pressure. TP24 The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. B46 The detachable protective housing for the loading and unloading valves of multi-unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator. N78 Packages consisting of inner glass, earthenware, or polyethylene or other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. (3) Damage to terminals. Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 C (115 F). UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . Unlined tanks must be passivated before being placed in service. 15, 1976, unless otherwise noted. IBCs must have a device to allow venting. A19 Combination packagings consisting of outer fiber drums or plywood drums, with inner plastic packagings, are not authorized for transportation by aircraft. When a placard is displayed, the placard must be the placard shown in 172.560. For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle are authorized for two years from the date of IBC manufacture. B35 Tank cars containing hydrogen cyanide may be alternatively marked Hydrocyanic acid, liquefied if otherwise conforming to marking requirements in subpart D of this part. The proper shipping name Paint related material, corrosive, flammable may be used for consignments of packages containing Paint, corrosive, flammable and Paint related material, corrosive, flammable in the same package; c. The proper shipping name Paint related material, flammable, corrosive may be used for consignments of packages containing Paint, flammable, corrosive and Paint related material, flammable, corrosive in the same package; and. Outage must be at least 5 percent at 98 C (208 F). If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, then the shipping paper must indicate both UN 3091 Lithium metal batteries packed with equipment and UN 3481 Lithium ion batteries packed with equipment.. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. TP16 The portable tank must be protected against over and under pressurization which may be experienced during transportation. TP30 This hazardous material may only be transported in insulated tanks. 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. B53 Packagings must be made of either aluminum or steel. N5 Glass materials of construction are not authorized for any part of a packaging which is normally in contact with the hazardous material. 430 This entry shall only be used for solid medical waste of Category A transported for disposal. During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ventilated place, away from all sources of heat. B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. For non-pressurized lighters containing a Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Administrator prior to being offered for transportation or transported in commerce. 2 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. Individual Name: Mr. David Comen. (a) The Hazardous Materials Table . B23 Tanks must be made of steel that is rubber lined or unlined. TP4 The maximum degree of filling for portable tanks must not exceed 90%. Each radiation detector must meet the following conditions: (1) The pressure in each neutron radiation detector must not exceed 105 kPa absolute at 20 C (68 F); (2) The amount of gas must not exceed 13 grams (0.45 ounces) per detector; and, (3) Each neutron radiation detector must be of welded metal construction with brazed metal to ceramic feed through assemblies. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. A5 Solids having an inhalation toxicity of Packing Group I are not permitted on passenger aircraft and may not exceed a maximum net quantity per package of 15 kg (33 pounds) on cargo aircraft. Packaging Authorizations (Column 8) Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. (7) The design type of the article must be subjected to the following test. (2) An indication of compliance with this special provision must be provided by marking each package with the words not restricted or by including the words not restricted on a transport document such as an air waybill accompanying the shipment. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending on its physical form at 55 C (131 F) at atmospheric pressure. This includes vehicles transported in a packaging. N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely surrounded with absorbent cushioning material. 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. The official, published CFR, is updated annually and available below under B70 If DOT 103ANW tank car tank is used: All cast metal in contact with the lading must have 96.7 percent nickel content; and the lading must be anhydrous and free from any impurities. j. c. Packagings are excepted from the design stress limits at elevated temperatures, as described in Section VIII of the ASME Code (IBR, see 171.7 of this subchapter). N20 A 5M1 multi-wall paper bag is authorized if transported in a closed transport vehicle. Such packages must be transported on cargo aircraft only. e. Transport in accordance with this special provision must be noted on the shipping paper. The packaging shall be designed for a working temperature of at least 121 C (250 F). It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 meters; and. Testing must be conducted on at least three packages as prepared for transport. Different Types of Solder- All Common Classifications (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. meet the venting requirements in 173.24(g) or (2.) When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code or codes, there may be several of them is in addition to the generalpackaging requirements of173.24and any other applicable packaging requirements in Part 173. A210 This substance is forbidden for transport by air. individual packaging placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet). A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier.

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